*********** 031692B.CHM *********** Country: Korea From: KORDI (Korea Ocean Research and Development Institute) 1990 Annual Report CHEMICAL OCEANOGRAPHY Chemical Oceanography Laboratory Marine Natural Products Chemistry Laboratory Chemical Oceanography Laboratory YANG, Dong Beom Head, Dr., Chemical Oceanography LEE, Soo Hyung Principal Research Scientist, Ph. D., Analytical Chemistry KIM, Eun Soo Senior Research Scientist, Ph. D., Chemical Oceanography OH, Jae Ryoung Senior Research Scientist, M. S., Analytical Chemistry The major goals of Chemical Oceanography Laboratory are to understand the chemical characteristics of the seas and the cycling of chemical substances in the marine ecosystem, and to develop conceptual and practical ways to protect the marine environment from increasing human perturbation. Development of analytical methods and instrumentation for the determination of chemical constituents and rates of oceanic processes in the marine environment is also one of the basic functions of the laboratory. We are concerned about not only the descriptive aspect, that is, the observable composition, but also the origin, fate and spatio-temporal variations of chemical constituents. This kind of study provides the data indispensable in understanding the diverse oceanic processes, and in establishing strategies for the use of marine resources and for the protection of the marine environment. The scarcity of important chemicaL constituents in the marine environment demands a great deal of sensitivity in the techniques to determine their concentration. Hence special emphasis is placed on improving and developing analytical techniques for the determination of trace metals and organics in seawater, biota and sediments. Efforts are also made to develop the measur- ing techniques to determine the rates of -material transfer and the micro- structure of biochemically important parameters in the marine environment. Natural ecosystems are activities where important transfers of organic matter and trace elements occur rapidly in a complex manner. The emphasis in this work is put on the studies of material transfer which define the rates mid fluxes of biogenic materials in the marine ecosystem and assess the behavior of diverse pollutants through the marine food web. How organisms affect and are effected by seawater and sediments are also studied. Ten research projects, composed of four supported by the Ministry of Science and Technology, three sponsored by private industries, and the three supported by KORDI have been carried out. The purpose of "A Study on the Development of Chemical and Microbiological Technology for the Control of Marine Oil Pollution(3rd year)" was to develop oil spill protection and clean-up technology. Computerized advance planning to countermeasure oil spills in the sea was also developed. Physico-chemical and microbiological studies were done to assess the environmental impacts of stranded oil and to prepare the suitable clean-up techniques. A personal computer-based Oil Spill Advance Planning, system named (KOSAP), was further extended for simulation models, environmental sensitivity maps, and decision- making program. The purpose of "A Study oil the Coastal Pollution and Monitoring (3rd year)" was to assess the present status of coastal pollution in Korea and to develop pollution monitoring techniques. Mussels were collected at 16 sampling sites located along the coastlines, and analyzed for 14 heavy metals in order to assess the metal pollution status of Korea; analysis was based on the world wide data obtained by the International Mussel Watch program. "A Study on the Atlas of Marine Resources in the Adjacent Seas to Korea (4th year of the South Sea)" is devoted to mapping chemical variables in the sea and providing basic data for marine resources in the Korean waters. Dissolved oxygen, Ph, dissolved nutrients and plant pigments were measured in the water column. In addition primary productivity was widely investigated in conjunction with nutrient and light regime. During the study on the "Marine Environmental Impact Assessments for the Wolsong Nuclear Power Plant", chemical constituents of the seawater in the vicinity of the nuclear power plant were measured because the cooling water might affect the marine ecosystem. "Marine Environmental Studies in the Cultivation Ground of laver in Haenam Bay" was performed since laver production in Haenam area was claimed to be largely affected by the construction of a tide embankment. Emphasis is laid on the behavior of nitrogenous nutrients which are essential for the growth of laver. Organic carbon and nitrogen contents of laver are studied to investigate the possible impact of changing nutrient fields on laver cultivation. The purpose of "Environmental Study around Tongyong-Anjong Industrial Complex" is to assess the impacts on the environment during the construction phase of the industrial site. Seasonal variations of environmental parameters are being carefully investigated because the adjacent seas are important aquacultural grounds. Institute - sponsored projects are "A Study on the Supplementation of Laboratory Manual for the Chemical Analysis of Pollutants", "Chemical Speciation of Trace Metals in Coastal Waters' and "Heavy Metal Compositions of Animals from Hydrothermal Vents and Coldwater Seeps." Marine Natural Products Chemistry Lab. HONG, Gi Hoon Head, Ph. D., Chemical Oceanography SHIN, Jongheon Senior Research Scientist, Ph.D.,Marine Natural Products Chemistry Marine Natural Products Chemistry : Marine Natural Products Chemistry, which is basically the chemical investigation of marine organisms, is a young field of science in Korea. Established in 1989, the Marine Natural Products Chemistry Laboratory focuses its research programs on the isolation and structural determination of biologically active metabolites from marine organisms. The major target organisms will be tunicates, sponges, gorgonians, and bryozoans found in the Korean and Antarctic waters. Among marine microorganisms, symbiotic bacteria and Actinomycetes will be primarily investigated for the isolation of novel biologically active substances. Additional research areas include: * Synthetic derivatization of marine natural products and screening for novel biological activities. * Chemical ecology of symbiotic marine bacteria and their hosts. * Chemosystematic study of colonial marine invertebrates. Ocean Biogeochemistry The Ocean Biogeochemistry Group is devoted to determining and understanding on a global scale, the processes controlling the time-varying fluxes of carbon and associated biogenic elements in the ocean, Moreover, the group is evaluating their related exchanges with the atmos- phere, sea floor, and continental boundaries.The ultimate goal is the development of a capability to understand the response of oceanic bio- geochemical processes to anthropogenic perturbation and climate change. The major research efforts are concentrated on the processes occurring in the upper water column, benthic regimes and sedimentary records using various tracers. Research Activities in 1990 Government-sponsored projects A Study on the Strategy for the Development of Deep Seabed Mineral Resources-Environmental Impacts (1st year) : This study is a part of the ongoing Deep Sea Mineral Exploitation Project of the Geology and Geophysical Research Division of KORDI. The objectives are : (1) to develop an environmental data base to meet the requirements of Korean and the international organization's marine environmental regulations, (2) to develop a first order predictive capability for determining potential environmental effects, and (3) to help develop an information base for the preparation of environmental guidelines for industry and government. In the first year, an extensive literature survey was produced to study national and international laws concerning the environmental protection, to collect the existing knowledge on the possible mining sites, and to develop oceanographic instrumentation to be used in the sea. Coastal Ocean Flux Study in the Mouth of the Yellow Sea (1st year) -The mouth, which is located in the southwestern part of the Yellow Sea, is very dynamic and heavily perturbed by humans among the continental shelves in the world. The objectives of the project are : (1) to evaluate the fluxes of biogenic elements across the mouth of the Yellow Sea, (2) to understand the formation of chlorophyll fronts and annual cycles of primary productivity, (3) to estimate fluxes of biogenic materials across the land and sea-floor boundaries, and (4) to link modern biogeochemical processes with the past biogeochemical sedimentary records. In the first year, the existing data were gathered and analyzed, and new time series sediment traps were tested, and shipboard analytical methods were elaborated. This project is recognized as a part of the Joint Global Ocean Flux Study (JGOFS) of the Scientific Committee on Oceanic Research (SCOR). JGOFS is one of the largest international efforts to understand global climate change. Industry-sponsored project Environmental Assessment of Suncheon Bay : This project was carried out along with the Chemical Oceanography Laboratory of KORDI. The impact of organic industrial waste discharge on the intermittently freshwater driven shallow marine bay was assessed. Early diagenesis of organic matter in the sediment column was also investigated. Institute-sponsored project Introduction to Chemical Oceanography : A text book of Chemical Oceanography with emphasis on bIogeochemistry, is being written for Korean marine scientists and students to introduce the role of oceans in the global climate change. Long-Term Research Plan on Marine Natural Products : A strategy is being developed to identify the needs of marine natural products since the Marine Natural Products Chemistry is quite new in Korea and requires state-of-the- art technology. International cooperation project KORDI participates in the International Atomic Energy Agency (IAEA) project, 'Marine contaminant and sediment transport (RAS/8 /065)." The objective is to understand sediment and contaminant transport processes in the marine environments utilizing the existing natural and man-made radionucildes. PROJECTS Government Sponsored: Environmental study for deep sea mineral exploitation July 1990 - July 1991: G. H. Hong A study, on the fluxes and cycling of chemicals in the mouth of Yellow Sea (Korean JGOFS program) July 1990-July 1991: G. H. Hong/S. H. Lee A study, on the atlas of marine resources in the adjacent Seas to Korea -South Sea Oct. 1989-Oct. 1990: K. S. Nam/S. H. Lee A study on the development of chemical and microbiological technology for the control of marine oil pollution Oct. 1989-Oct. 1990: D. B. Yang A study on the coastal water pollution and monitoring Oct. 1989-Oct. 1990: S. H. Lee A study on the process and the evolution of coastal pollution July 1990- June 1991: D. B. Yang Industry Sponsored Environmental assessment of Suncheon Bay (Bohae Industrial Co.) May 1989-Apr. 1990: G. H. Hong/C. K. Kim Oceanographic survey, in the adjacent seas to the Wolsong Nuclear Power Plant (Korea Electric Power Corp.) Nov. 1989-Dec. 1990: S. W. Kang/D. B. Yang Marine environmental studies in the cultivation ground of Larvae in Haenam area ( Haenam Farmland Improvement Association) July 1990-May 1991: D. B. Yang Environmental study around Tongyong-Anjong Industrial Complex (The Korea Land Development Corporation) Sep. 1990-Nov. 1991: J. R. Oh Institute Sponsored: Introduction to Chemical Oceanography May 1990-Apr. 1991: G. H. Hong/S. H. Lee Long term research plan on marine natural products Sep. 1990-Apr. 1991: J. H. Shin A study on the assessment technique of marine environment May 1990- Apr. 1991: D. B. Yang Chemical speciation of trace metals in coastal waters Sep. 1990-Apr. 1991: J. R. Oh Heavy metal compositions of animals from hydrothermal vents and coldwater seeps Nov. 1990-Apr. 1991: E. S. Kim REFERENCES Han, M. W. and H. I. Yoon. Effect of sea salts in the major anion distribution in an ice core of the Fildes Peninsula ice field : A preliminary study result. Kor. J. Pol. Res. 1(2) : 17 - 24. Lee, S. H., K. T. Kim and S. H. Kim. Trace metals in the surface waters of Maxwell Bay, King George Island, Antarctica. Kor. J. Pol. Res. 1(2) : 11- 16. Suk, B. C., T. Nakamura *, N. Nakai *, and A. Taira*. Radio-carbon age determination by Tandem Accelerator Mass Spectrometry technique and its application to the Korean Seas. Quat. Res. 4(1) : 27-40. Yang, J. S. and D. S. Jeon. Determination of organophosphorus pesticides in Suncheon Bay. J. Oceanol. Soc. Korea 25(1) : 21- 25. ************** END Msg. B.CHM **************